Elusive group 14 elemental species stabilized by amidinato silylenes

• 主要作者: Wee, Meldon Yi Shuo
• 其他作者: So Cheuk Wai
• 格式: Thesis-Doctor of Philosophy
• 語言: English
• 出版: Nanyang Technological University 2024
• 主題: Science::Chemistry::Inorganic chemistry::Cyclic compounds; Science::Chemistry::Inorganic chemistry::Synthesis
• 在線閱讀: https://hdl.handle.net/10356/173285
• 機構: Nanyang Technological University

This thesis describes the synthesis and isolation of a series of Group 14 elemental clusters bearing challenging and unique structural characteristics, all stabilized by an amidinato silylene ligand system. In Chapter 2, the synthesis of a remarkable heavier analogue of spiro[3.3]hepta-1,2,5,...