Elusive group 14 elemental species stabilized by amidinato silylenes

• المؤلف الرئيسي: Wee, Meldon Yi Shuo
• مؤلفون آخرون: So Cheuk Wai
• التنسيق: Thesis-Doctor of Philosophy
• اللغة: English
• منشور في: Nanyang Technological University 2024
• الموضوعات: Science::Chemistry::Inorganic chemistry::Cyclic compounds; Science::Chemistry::Inorganic chemistry::Synthesis
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/173285

This thesis describes the synthesis and isolation of a series of Group 14 elemental clusters bearing challenging and unique structural characteristics, all stabilized by an amidinato silylene ligand system. In Chapter 2, the synthesis of a remarkable heavier analogue of spiro[3.3]hepta-1,2,5,...