Synthesis and properties of the perfluoroethyl martin silicate: reactivity in solution and solid-state mechanochemistry
We herein report the first synthesis of a Martin silicate bearing a pentafluoroethyl chain. The full characterisation of this new pentacoordinated silicon species is detailed. Insights on its electronic properties based on structural, physicochemical and computational data are provided. A comparativ...
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sg-ntu-dr.10356-1740602024-03-18T15:35:39Z Synthesis and properties of the perfluoroethyl martin silicate: reactivity in solution and solid-state mechanochemistry Millanvois, Alexandre Tan, Choon-Hong Ollivier, Cyril Fensterbank, Louis School of Physical and Mathematical Sciences Chemistry Martin spirosilane Mechanochemistry We herein report the first synthesis of a Martin silicate bearing a pentafluoroethyl chain. The full characterisation of this new pentacoordinated silicon species is detailed. Insights on its electronic properties based on structural, physicochemical and computational data are provided. A comparative study of reactivity in solution and in solid state by mechanochemistry has been performed in order to assess the ability of this bench-stable salt to act as a safe C2F5-alkylation reagent in a nucleophilic or radical manner. Published version 2024-03-13T02:47:32Z 2024-03-13T02:47:32Z 2023 Journal Article Millanvois, A., Tan, C., Ollivier, C. & Fensterbank, L. (2023). Synthesis and properties of the perfluoroethyl martin silicate: reactivity in solution and solid-state mechanochemistry. European Journal of Organic Chemistry, 26(18), e202300223-. https://dx.doi.org/10.1002/ejoc.202300223 1434-193X https://hdl.handle.net/10356/174060 10.1002/ejoc.202300223 2-s2.0-85153386549 18 26 e202300223 en European Journal of Organic Chemistry © 2023 The Authors. European Journal of Organic Chemistry published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made. application/pdf |
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Chemistry Martin spirosilane Mechanochemistry |
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Chemistry Martin spirosilane Mechanochemistry Millanvois, Alexandre Tan, Choon-Hong Ollivier, Cyril Fensterbank, Louis Synthesis and properties of the perfluoroethyl martin silicate: reactivity in solution and solid-state mechanochemistry |
| description |
We herein report the first synthesis of a Martin silicate bearing a pentafluoroethyl chain. The full characterisation of this new pentacoordinated silicon species is detailed. Insights on its electronic properties based on structural, physicochemical and computational data are provided. A comparative study of reactivity in solution and in solid state by mechanochemistry has been performed in order to assess the ability of this bench-stable salt to act as a safe C2F5-alkylation reagent in a nucleophilic or radical manner. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Millanvois, Alexandre Tan, Choon-Hong Ollivier, Cyril Fensterbank, Louis |
| format |
Article |
| author |
Millanvois, Alexandre Tan, Choon-Hong Ollivier, Cyril Fensterbank, Louis |
| author_sort |
Millanvois, Alexandre |
| title |
Synthesis and properties of the perfluoroethyl martin silicate: reactivity in solution and solid-state mechanochemistry |
| title_short |
Synthesis and properties of the perfluoroethyl martin silicate: reactivity in solution and solid-state mechanochemistry |
| title_full |
Synthesis and properties of the perfluoroethyl martin silicate: reactivity in solution and solid-state mechanochemistry |
| title_fullStr |
Synthesis and properties of the perfluoroethyl martin silicate: reactivity in solution and solid-state mechanochemistry |
| title_full_unstemmed |
Synthesis and properties of the perfluoroethyl martin silicate: reactivity in solution and solid-state mechanochemistry |
| title_sort |
synthesis and properties of the perfluoroethyl martin silicate: reactivity in solution and solid-state mechanochemistry |
| publishDate |
2024 |
| url |
https://hdl.handle.net/10356/174060 |
| _version_ |
1794549364612399104 |