Synthesis and properties of the perfluoroethyl martin silicate: reactivity in solution and solid-state mechanochemistry

• Main Authors: Millanvois, Alexandre, Tan, Choon-Hong, Ollivier, Cyril, Fensterbank, Louis
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2024
• Subjects: Chemistry; Martin spirosilane; Mechanochemistry
• Online Access: https://hdl.handle.net/10356/174060
• Institution: Nanyang Technological University

We herein report the first synthesis of a Martin silicate bearing a pentafluoroethyl chain. The full characterisation of this new pentacoordinated silicon species is detailed. Insights on its electronic properties based on structural, physicochemical and computational data are provided. A comparativ...