Reactions of main group compounds with azides forming organic nitrogen-containing species
Since the seminal discovery of phenyl azide by Grieß in 1864, a variety of organic azides (R-N3) have been developed and extensively studied. The amenability of azides to a number of reactions has expanded their utility as building blocks not only in organic synthesis but also in bioorthogonal chemi...
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sg-ntu-dr.10356-1742352024-03-22T15:31:51Z Reactions of main group compounds with azides forming organic nitrogen-containing species Zhu, Lizhao Kinjo, Rei School of Chemistry, Chemical Engineering and Biotechnology Chemistry Bioorthogonal chemistries Organic nitrogen Since the seminal discovery of phenyl azide by Grieß in 1864, a variety of organic azides (R-N3) have been developed and extensively studied. The amenability of azides to a number of reactions has expanded their utility as building blocks not only in organic synthesis but also in bioorthogonal chemistry and materials science. Over the decades, it has been demonstrated that the reactions of main group compounds with azides lead to diverse N-containing main group molecules. In view of the pronounced progress in this area, this review summarizes the reactions of main group compounds with azides, emphatically introducing their reaction patterns and mechanisms. The reactions of forming inorganic nitrogen species are not included in this review. Ministry of Education (MOE) Submitted/Accepted version We are grateful to Nanyang Technological University (NTU), Nippon Shokubai, and the Singapore Ministry of Education (MOET2EP10220-0002) for financial support. 2024-03-22T05:45:01Z 2024-03-22T05:45:01Z 2023 Journal Article Zhu, L. & Kinjo, R. (2023). Reactions of main group compounds with azides forming organic nitrogen-containing species. Chemical Society Reviews, 52(16), 5563-5606. https://dx.doi.org/10.1039/d3cs00290j 0306-0012 https://hdl.handle.net/10356/174235 10.1039/d3cs00290j 37519098 2-s2.0-85167425147 16 52 5563 5606 en MOET2EP10220-0002 Chemical Society Reviews © 2023 The Author(s). All rights reserved. This article may be downloaded for personal use only. Any other use requires prior permission of the copyright holder. The Version of Record is available online at http://doi.org/10.1039/D3CS00290J. application/pdf |
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Chemistry Bioorthogonal chemistries Organic nitrogen Zhu, Lizhao Kinjo, Rei Reactions of main group compounds with azides forming organic nitrogen-containing species |
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Since the seminal discovery of phenyl azide by Grieß in 1864, a variety of organic azides (R-N3) have been developed and extensively studied. The amenability of azides to a number of reactions has expanded their utility as building blocks not only in organic synthesis but also in bioorthogonal chemistry and materials science. Over the decades, it has been demonstrated that the reactions of main group compounds with azides lead to diverse N-containing main group molecules. In view of the pronounced progress in this area, this review summarizes the reactions of main group compounds with azides, emphatically introducing their reaction patterns and mechanisms. The reactions of forming inorganic nitrogen species are not included in this review. |
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School of Chemistry, Chemical Engineering and Biotechnology |
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School of Chemistry, Chemical Engineering and Biotechnology Zhu, Lizhao Kinjo, Rei |
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Article |
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Zhu, Lizhao Kinjo, Rei |
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Zhu, Lizhao |
title |
Reactions of main group compounds with azides forming organic nitrogen-containing species |
title_short |
Reactions of main group compounds with azides forming organic nitrogen-containing species |
title_full |
Reactions of main group compounds with azides forming organic nitrogen-containing species |
title_fullStr |
Reactions of main group compounds with azides forming organic nitrogen-containing species |
title_full_unstemmed |
Reactions of main group compounds with azides forming organic nitrogen-containing species |
title_sort |
reactions of main group compounds with azides forming organic nitrogen-containing species |
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2024 |
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https://hdl.handle.net/10356/174235 |
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