Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation

Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation

4-CN-pyridine is a widely applied 4-pyridinylation reagent for diverse transformations. Conventionally, the reaction proceeds via an open-shell radical cross-coupling pathway. Following our previous study, in this work, we report the Pd-catalyzed allyl 4-pyrinylation reaction under electrochemical c...

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Main Authors: Ding, Wei-Jie, Yang, Chun-Hui, Feng, Zhongtao, Lu, Shi-Rong, Cheng, Xu
Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
Format: Article
Language:English
Published: 2024
Subjects:
Chemistry
Electrochemistry
Palladium
Online Access:https://hdl.handle.net/10356/179900
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1799002024-09-06T15:31:48Z Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation Ding, Wei-Jie Yang, Chun-Hui Feng, Zhongtao Lu, Shi-Rong Cheng, Xu School of Chemistry, Chemical Engineering and Biotechnology Chemistry Electrochemistry Palladium 4-CN-pyridine is a widely applied 4-pyridinylation reagent for diverse transformations. Conventionally, the reaction proceeds via an open-shell radical cross-coupling pathway. Following our previous study, in this work, we report the Pd-catalyzed allyl 4-pyrinylation reaction under electrochemical conditions. The reaction proceeds via radical-polar crossover pathway in which the role of phosphine ligand in reactivity and selectivity was extensively investigated. Published version This work was supported by the National Natural Science Foundation of China (Nos. 22031008 and 22071105). 2024-09-02T04:21:38Z 2024-09-02T04:21:38Z 2024 Journal Article Ding, W., Yang, C., Feng, Z., Lu, S. & Cheng, X. (2024). Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation. Journal of Electrochemistry, 30(5), 3438-. https://dx.doi.org/10.61558/2993-074X.3438 1006-3471 https://hdl.handle.net/10356/179900 10.61558/2993-074X.3438 2-s2.0-85195826745 5 30 3438 en Journal of Electrochemistry © 2024 Xiamen University and Chinese Chemical Society. This is an open access article under the CC BY 4.0 license (https://creativecommons.org/licenses/by/4.0/). application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Chemistry
Electrochemistry
Palladium
spellingShingle Chemistry
Electrochemistry
Palladium
Ding, Wei-Jie
Yang, Chun-Hui
Feng, Zhongtao
Lu, Shi-Rong
Cheng, Xu
Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation
description 4-CN-pyridine is a widely applied 4-pyridinylation reagent for diverse transformations. Conventionally, the reaction proceeds via an open-shell radical cross-coupling pathway. Following our previous study, in this work, we report the Pd-catalyzed allyl 4-pyrinylation reaction under electrochemical conditions. The reaction proceeds via radical-polar crossover pathway in which the role of phosphine ligand in reactivity and selectivity was extensively investigated.
author2 School of Chemistry, Chemical Engineering and Biotechnology
author_facet School of Chemistry, Chemical Engineering and Biotechnology
Ding, Wei-Jie
Yang, Chun-Hui
Feng, Zhongtao
Lu, Shi-Rong
Cheng, Xu
format Article
author Ding, Wei-Jie
Yang, Chun-Hui
Feng, Zhongtao
Lu, Shi-Rong
Cheng, Xu
author_sort Ding, Wei-Jie
title Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation
title_short Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation
title_full Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation
title_fullStr Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation
title_full_unstemmed Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation
title_sort comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation
publishDate 2024
url https://hdl.handle.net/10356/179900
_version_ 1814047448716279808

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