Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation
4-CN-pyridine is a widely applied 4-pyridinylation reagent for diverse transformations. Conventionally, the reaction proceeds via an open-shell radical cross-coupling pathway. Following our previous study, in this work, we report the Pd-catalyzed allyl 4-pyrinylation reaction under electrochemical c...
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sg-ntu-dr.10356-1799002024-09-06T15:31:48Z Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation Ding, Wei-Jie Yang, Chun-Hui Feng, Zhongtao Lu, Shi-Rong Cheng, Xu School of Chemistry, Chemical Engineering and Biotechnology Chemistry Electrochemistry Palladium 4-CN-pyridine is a widely applied 4-pyridinylation reagent for diverse transformations. Conventionally, the reaction proceeds via an open-shell radical cross-coupling pathway. Following our previous study, in this work, we report the Pd-catalyzed allyl 4-pyrinylation reaction under electrochemical conditions. The reaction proceeds via radical-polar crossover pathway in which the role of phosphine ligand in reactivity and selectivity was extensively investigated. Published version This work was supported by the National Natural Science Foundation of China (Nos. 22031008 and 22071105). 2024-09-02T04:21:38Z 2024-09-02T04:21:38Z 2024 Journal Article Ding, W., Yang, C., Feng, Z., Lu, S. & Cheng, X. (2024). Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation. Journal of Electrochemistry, 30(5), 3438-. https://dx.doi.org/10.61558/2993-074X.3438 1006-3471 https://hdl.handle.net/10356/179900 10.61558/2993-074X.3438 2-s2.0-85195826745 5 30 3438 en Journal of Electrochemistry © 2024 Xiamen University and Chinese Chemical Society. This is an open access article under the CC BY 4.0 license (https://creativecommons.org/licenses/by/4.0/). application/pdf |
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Chemistry Electrochemistry Palladium Ding, Wei-Jie Yang, Chun-Hui Feng, Zhongtao Lu, Shi-Rong Cheng, Xu Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation |
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4-CN-pyridine is a widely applied 4-pyridinylation reagent for diverse transformations. Conventionally, the reaction proceeds via an open-shell radical cross-coupling pathway. Following our previous study, in this work, we report the Pd-catalyzed allyl 4-pyrinylation reaction under electrochemical conditions. The reaction proceeds via radical-polar crossover pathway in which the role of phosphine ligand in reactivity and selectivity was extensively investigated. |
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School of Chemistry, Chemical Engineering and Biotechnology |
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School of Chemistry, Chemical Engineering and Biotechnology Ding, Wei-Jie Yang, Chun-Hui Feng, Zhongtao Lu, Shi-Rong Cheng, Xu |
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Article |
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Ding, Wei-Jie Yang, Chun-Hui Feng, Zhongtao Lu, Shi-Rong Cheng, Xu |
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Ding, Wei-Jie |
title |
Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation |
title_short |
Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation |
title_full |
Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation |
title_fullStr |
Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation |
title_full_unstemmed |
Comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation |
title_sort |
comparison of ligands in palladium-catalyzed electrochemical allyl 4-pyridinylation |
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2024 |
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https://hdl.handle.net/10356/179900 |
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