Ultraflat Cu(111) foils by surface acoustic wave-assisted annealing

Ultraflat metal foils are essential for semiconductor nanoelectronics applications and nanomaterial epitaxial growth. Numerous efforts have been devoted to metal surface engineering studies in the past decades. However, various challenges persist, including size limitations, polishing non-uniformiti...

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Main Authors: Tian, Bo, Li, Junzhu, Wang, Qingxiao, Samad, Abdus, Yuan, Yue, Hedhili, Mohamed Nejib, Jangir, Arun, Gruenewald, Marco, Lanza, Mario, Schwingenschlögl, Udo, Fritz, Torsten, Zhang, Xixiang, Liu, Zheng
Other Authors: School of Materials Science and Engineering
Format: Article
Language:English
Published: 2025
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Online Access:https://hdl.handle.net/10356/182075
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1820752025-01-10T15:50:23Z Ultraflat Cu(111) foils by surface acoustic wave-assisted annealing Tian, Bo Li, Junzhu Wang, Qingxiao Samad, Abdus Yuan, Yue Hedhili, Mohamed Nejib Jangir, Arun Gruenewald, Marco Lanza, Mario Schwingenschlögl, Udo Fritz, Torsten Zhang, Xixiang Liu, Zheng School of Materials Science and Engineering Engineering Acoustic wave Annealing Ultraflat metal foils are essential for semiconductor nanoelectronics applications and nanomaterial epitaxial growth. Numerous efforts have been devoted to metal surface engineering studies in the past decades. However, various challenges persist, including size limitations, polishing non-uniformities, and undesired contaminants. Thus, further exploration of advanced metal surface treatment techniques is essential. Here, we report a physical strategy that utilizes surface acoustic wave assisted annealing to flatten metal foils by eliminating the surface steps, eventually transforming commercial rough metal foils into ultraflat substrates. Large-area, high-quality, smooth 2D materials, including graphene and hexagonal boron nitride (hBN), were successfully grown on the resulting flat metal substrates. Further investigation into the oxidation of 2D-material-coated metal foils, both rough and flat, revealed that the hBN-coated flat metal foil exhibits enhanced anti-corrosion properties. Molecular dynamics simulations and density functional theory validate our experimental observations. Agency for Science, Technology and Research (A*STAR) National Research Foundation (NRF) Published version This project was supported by the National Research Foundation Singapore (NRF-CRP22-2019-0007, NRF-CRP26-2021-0004), DSO National Laboratories under the AI Singapore Program (AISG2-GC-2023-009), and A*STAR under its MTC Programmatic Grant (M23M2b0056) (Z.L.). This work was also supported by the King Abdullah University of Science and Technology (KAUST), under the Semiconductor Initiative – Emerging Semiconductor Materials Thrust (X.Z.). 2025-01-07T02:13:05Z 2025-01-07T02:13:05Z 2024 Journal Article Tian, B., Li, J., Wang, Q., Samad, A., Yuan, Y., Hedhili, M. N., Jangir, A., Gruenewald, M., Lanza, M., Schwingenschlögl, U., Fritz, T., Zhang, X. & Liu, Z. (2024). Ultraflat Cu(111) foils by surface acoustic wave-assisted annealing. Nature Communications, 15(1), 9488-. https://dx.doi.org/10.1038/s41467-024-53573-y 2041-1723 https://hdl.handle.net/10356/182075 10.1038/s41467-024-53573-y 39488536 2-s2.0-85208290466 1 15 9488 en NRF-CRP22-2019-0007 NRF- CRP26-2021-0004 AISG2-GC-2023-009 M23M2b0056 Nature Communications © 2024 The Author(s). Open Access. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/ licenses/by/4.0/. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Engineering
Acoustic wave
Annealing
spellingShingle Engineering
Acoustic wave
Annealing
Tian, Bo
Li, Junzhu
Wang, Qingxiao
Samad, Abdus
Yuan, Yue
Hedhili, Mohamed Nejib
Jangir, Arun
Gruenewald, Marco
Lanza, Mario
Schwingenschlögl, Udo
Fritz, Torsten
Zhang, Xixiang
Liu, Zheng
Ultraflat Cu(111) foils by surface acoustic wave-assisted annealing
description Ultraflat metal foils are essential for semiconductor nanoelectronics applications and nanomaterial epitaxial growth. Numerous efforts have been devoted to metal surface engineering studies in the past decades. However, various challenges persist, including size limitations, polishing non-uniformities, and undesired contaminants. Thus, further exploration of advanced metal surface treatment techniques is essential. Here, we report a physical strategy that utilizes surface acoustic wave assisted annealing to flatten metal foils by eliminating the surface steps, eventually transforming commercial rough metal foils into ultraflat substrates. Large-area, high-quality, smooth 2D materials, including graphene and hexagonal boron nitride (hBN), were successfully grown on the resulting flat metal substrates. Further investigation into the oxidation of 2D-material-coated metal foils, both rough and flat, revealed that the hBN-coated flat metal foil exhibits enhanced anti-corrosion properties. Molecular dynamics simulations and density functional theory validate our experimental observations.
author2 School of Materials Science and Engineering
author_facet School of Materials Science and Engineering
Tian, Bo
Li, Junzhu
Wang, Qingxiao
Samad, Abdus
Yuan, Yue
Hedhili, Mohamed Nejib
Jangir, Arun
Gruenewald, Marco
Lanza, Mario
Schwingenschlögl, Udo
Fritz, Torsten
Zhang, Xixiang
Liu, Zheng
format Article
author Tian, Bo
Li, Junzhu
Wang, Qingxiao
Samad, Abdus
Yuan, Yue
Hedhili, Mohamed Nejib
Jangir, Arun
Gruenewald, Marco
Lanza, Mario
Schwingenschlögl, Udo
Fritz, Torsten
Zhang, Xixiang
Liu, Zheng
author_sort Tian, Bo
title Ultraflat Cu(111) foils by surface acoustic wave-assisted annealing
title_short Ultraflat Cu(111) foils by surface acoustic wave-assisted annealing
title_full Ultraflat Cu(111) foils by surface acoustic wave-assisted annealing
title_fullStr Ultraflat Cu(111) foils by surface acoustic wave-assisted annealing
title_full_unstemmed Ultraflat Cu(111) foils by surface acoustic wave-assisted annealing
title_sort ultraflat cu(111) foils by surface acoustic wave-assisted annealing
publishDate 2025
url https://hdl.handle.net/10356/182075
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