Synthesis of dihydrogambirtannine by alkyne [2 + 2 + 2]-cyclotrimerisation
The first asymmetric synthesis of (−)-dihydrogambirtannine has been achieved using nucleophilic addition to a chiral sulfinyl imine to establish the stereogenic centre and [2 + 2 + 2] alkyne cyclotrimerisation to construct the aromatic E ring.
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| Main Authors: | , , , , |
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| 其他作者: | |
| 格式: | Article |
| 語言: | English |
| 出版: |
2025
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| 主題: | |
| 在線閱讀: | https://hdl.handle.net/10356/182986 |
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| 機構: | Nanyang Technological University |
| 語言: | English |
| 總結: | The first asymmetric synthesis of (−)-dihydrogambirtannine has been achieved using nucleophilic addition to a chiral sulfinyl imine to establish the stereogenic centre and [2 + 2 + 2] alkyne cyclotrimerisation to construct the aromatic E ring. |
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