Boronic acid and phosphoyl chloride-mediated site-selective ketalization of unprotected saccharides: in situ generation of aproton catalyst and multiple roles of reagents

• المؤلفون الرئيسيون: Dai, Shuolu, Teng, Minggang, Xu, Erjuan, Xu, Min, Luo, Min, Chen, Chen, Chai, Huifang, Chi, Robin Yonggui, Wu, Jian, Lv, Wen-Xin
• مؤلفون آخرون: School of Chemistry, Chemical Engineering and Biotechnology
• التنسيق: مقال
• اللغة: English
• منشور في: 2025
• الموضوعات: Chemistry; Saccharides; Degradation
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/183584
• المؤسسة: Nanyang Technological University

In the chemical synthesis or modification of saccharides, regioselective protection of the many similar OH groups in saccharides is necessary but remains a major challenge. In particular, the regio- and stereoselective conversion of C(1,2)-OH has great synthetic potential in carbohydrate synthesis b...