Formation of novel polycyclic P-S-P linked complex through an unexpected stepwise [4+4] cycloaddition.
In this project we wish to report our findings on the synthesis of a P-S-P linked bidentate ligand, compound 1 from the precursor, bis[(3,4-dimethylphosphole) pentacarbonyltungsten]sulfide, 2. While in the preparation of compound 2, it was discovered that undergoes a [2+2] cycloaddition to form 3, f...
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Format: | Final Year Project |
Language: | English |
Published: |
2010
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Online Access: | http://hdl.handle.net/10356/39408 |
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Institution: | Nanyang Technological University |
Language: | English |
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