Formation of novel polycyclic P-S-P linked complex through an unexpected stepwise [4+4] cycloaddition.

In this project we wish to report our findings on the synthesis of a P-S-P linked bidentate ligand, compound 1 from the precursor, bis[(3,4-dimethylphosphole) pentacarbonyltungsten]sulfide, 2. While in the preparation of compound 2, it was discovered that undergoes a [2+2] cycloaddition to form 3, f...

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Bibliographic Details
Main Author: Lin, Yu Han.
Other Authors: School of Physical and Mathematical Sciences
Format: Final Year Project
Language:English
Published: 2010
Subjects:
Online Access:http://hdl.handle.net/10356/39408
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Institution: Nanyang Technological University
Language: English
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