Synthesis, mechanism studies of rhodium complexes and electrochemical oxidation, spectroscopic properties of phenol derivatives
A series of rare five-coordinate organorhodium(III) intermediates [Rh(N^C)(PAr3)2CH=CHR]PF6 (N^C = benzo[h,f]quinoline, benzo[h]quinoline, 2-phenylpyridine, R = para-Ph-(SO2CF3, CF3, NO2, Cl, F, H, CH3, OCH3), CH2Ph, CH2CH2Ph, Ar = para-Ph-(OCH3, CH3, F)) and subsequent C–C coupling rhodium(I) compl...
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| Format: | Theses and Dissertations |
| Language: | English |
| Published: |
2011
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| Online Access: | https://hdl.handle.net/10356/46283 |
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| Institution: | Nanyang Technological University |
| Language: | English |