Synthesis, mechanism studies of rhodium complexes and electrochemical oxidation, spectroscopic properties of phenol derivatives

• Main Author: Chen, Shan Shan
• Other Authors: Li Xingwei
• Format: Theses and Dissertations
• Language: English
• Published: 2011
• Subjects: DRNTU::Science::Chemistry
• Online Access: https://hdl.handle.net/10356/46283
• Institution: Nanyang Technological University

A series of rare five-coordinate organorhodium(III) intermediates [Rh(N^C)(PAr3)2CH=CHR]PF6 (N^C = benzo[h,f]quinoline, benzo[h]quinoline, 2-phenylpyridine, R = para-Ph-(SO2CF3, CF3, NO2, Cl, F, H, CH3, OCH3), CH2Ph, CH2CH2Ph, Ar = para-Ph-(OCH3, CH3, F)) and subsequent C–C coupling rhodium(I) compl...