Part I: Development of a base-free methodology for the nh-catalyzed intermolecular stetter reaction. Part II: Chiral anion mediated asymmetric stetter reaction

118 p.

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Bibliographic Details
Main Author:	Choo, En
Other Authors:	Loh Teck Peng
Format:	Theses and Dissertations
Published:	2011
Subjects:	DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Online Access:	http://hdl.handle.net/10356/47514
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Institution:	Nanyang Technological University

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spelling	sg-ntu-dr.10356-475142023-02-28T23:46:52Z Part I: Development of a base-free methodology for the nh-catalyzed intermolecular stetter reaction. Part II: Chiral anion mediated asymmetric stetter reaction Choo, En Loh Teck Peng School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis 118 p. We succeeded in developing a base-free methodology for the NHC-catalyzed intermolecular Stetter reaction by employing CsF as a dual Lewis acid/base activating reagent, achieving the desired 1,4-dicarbonyl structural scaffold under ultrasonication reaction condition. Generally, moderate to excellent yields were obtained. Yields were especially good when highly reactive Michael acceptors were employed in conjuction with an aromatic carbinol carrying electron withrdrawing subtituents. Master of Science 2011-12-27T08:31:55Z 2011-12-27T08:31:55Z 2009 2009 Thesis http://hdl.handle.net/10356/47514 Nanyang Technological University application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
topic	DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
spellingShingle	DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis Choo, En Part I: Development of a base-free methodology for the nh-catalyzed intermolecular stetter reaction. Part II: Chiral anion mediated asymmetric stetter reaction
description	118 p.
author2	Loh Teck Peng
author_facet	Loh Teck Peng Choo, En
format	Theses and Dissertations
author	Choo, En
author_sort	Choo, En
title	Part I: Development of a base-free methodology for the nh-catalyzed intermolecular stetter reaction. Part II: Chiral anion mediated asymmetric stetter reaction
title_short	Part I: Development of a base-free methodology for the nh-catalyzed intermolecular stetter reaction. Part II: Chiral anion mediated asymmetric stetter reaction
title_full	Part I: Development of a base-free methodology for the nh-catalyzed intermolecular stetter reaction. Part II: Chiral anion mediated asymmetric stetter reaction
title_fullStr	Part I: Development of a base-free methodology for the nh-catalyzed intermolecular stetter reaction. Part II: Chiral anion mediated asymmetric stetter reaction
title_full_unstemmed	Part I: Development of a base-free methodology for the nh-catalyzed intermolecular stetter reaction. Part II: Chiral anion mediated asymmetric stetter reaction
title_sort	part i: development of a base-free methodology for the nh-catalyzed intermolecular stetter reaction. part ii: chiral anion mediated asymmetric stetter reaction
publishDate	2011
url	http://hdl.handle.net/10356/47514
_version_	1759855788042485760

Part I: Development of a base-free methodology for the nh-catalyzed intermolecular stetter reaction. Part II: Chiral anion mediated asymmetric stetter reaction

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