Palladium-catalyzed allylic alkylation of enamides and allylic acetates
Functionalization of enamides via allylic alkylation was achieved under the catalysis of palladium. The 5-membered N-(1H-inden-3-yl)acetamides afforded the corresponding allylic alkylation products 3 in high yields. On the other hand, the 6-membered N-(3,4- dihydronaphthalen-1-yl)acetamides...
Saved in:
| Main Author: | |
|---|---|
| Other Authors: | |
| Format: | Theses and Dissertations |
| Language: | English |
| Published: |
2012
|
| Subjects: | |
| Online Access: | http://hdl.handle.net/10356/47993 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Nanyang Technological University |
| Language: | English |
| id |
sg-ntu-dr.10356-47993 |
|---|---|
| record_format |
dspace |
| spelling |
sg-ntu-dr.10356-479932023-02-28T23:45:28Z Palladium-catalyzed allylic alkylation of enamides and allylic acetates Lim, Juan Mei Loh Teck Peng School of Physical and Mathematical Sciences DRNTU::Science Functionalization of enamides via allylic alkylation was achieved under the catalysis of palladium. The 5-membered N-(1H-inden-3-yl)acetamides afforded the corresponding allylic alkylation products 3 in high yields. On the other hand, the 6-membered N-(3,4- dihydronaphthalen-1-yl)acetamides besides giving 3 in moderate yields, also provided another product 3’, wherein the enamide functional group had been hydrolyzed to a ketone group. Master of Science 2012-02-02T06:45:04Z 2012-02-02T06:45:04Z 2012 2012 Thesis http://hdl.handle.net/10356/47993 en 39 p. application/pdf |
| institution |
Nanyang Technological University |
| building |
NTU Library |
| continent |
Asia |
| country |
Singapore Singapore |
| content_provider |
NTU Library |
| collection |
DR-NTU |
| language |
English |
| topic |
DRNTU::Science |
| spellingShingle |
DRNTU::Science Lim, Juan Mei Palladium-catalyzed allylic alkylation of enamides and allylic acetates |
| description |
Functionalization of enamides via allylic alkylation was achieved under the catalysis of
palladium. The 5-membered N-(1H-inden-3-yl)acetamides afforded the corresponding allylic
alkylation products 3 in high yields. On the other hand, the 6-membered N-(3,4-
dihydronaphthalen-1-yl)acetamides besides giving 3 in moderate yields, also provided
another product 3’, wherein the enamide functional group had been hydrolyzed to a ketone
group. |
| author2 |
Loh Teck Peng |
| author_facet |
Loh Teck Peng Lim, Juan Mei |
| format |
Theses and Dissertations |
| author |
Lim, Juan Mei |
| author_sort |
Lim, Juan Mei |
| title |
Palladium-catalyzed allylic alkylation of enamides and allylic acetates |
| title_short |
Palladium-catalyzed allylic alkylation of enamides and allylic acetates |
| title_full |
Palladium-catalyzed allylic alkylation of enamides and allylic acetates |
| title_fullStr |
Palladium-catalyzed allylic alkylation of enamides and allylic acetates |
| title_full_unstemmed |
Palladium-catalyzed allylic alkylation of enamides and allylic acetates |
| title_sort |
palladium-catalyzed allylic alkylation of enamides and allylic acetates |
| publishDate |
2012 |
| url |
http://hdl.handle.net/10356/47993 |
| _version_ |
1759855542175531008 |