Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation

• المؤلفون الرئيسيون: Ding, Feiqing, William, Ronny, Wang, Fei, Liu, Xue-Wei
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2013
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/101076; http://hdl.handle.net/10220/11099

A highly efficient metal-free intermolecular C(sp3)–C(sp3) allyl–allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.