Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation
A highly efficient metal-free intermolecular C(sp3)–C(sp3) allyl–allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/101076 http://hdl.handle.net/10220/11099 |
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| Institution: | Nanyang Technological University |
| Language: | English |
| Summary: | A highly efficient metal-free intermolecular C(sp3)–C(sp3) allyl–allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed. |
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