Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation

A highly efficient metal-free intermolecular C(sp3)–C(sp3) allyl–allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.

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Main Authors: Ding, Feiqing, William, Ronny, Wang, Fei, Liu, Xue-Wei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/101076
http://hdl.handle.net/10220/11099
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1010762020-03-07T12:34:53Z Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation Ding, Feiqing William, Ronny Wang, Fei Liu, Xue-Wei School of Physical and Mathematical Sciences A highly efficient metal-free intermolecular C(sp3)–C(sp3) allyl–allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed. 2013-07-10T04:31:32Z 2019-12-06T20:33:06Z 2013-07-10T04:31:32Z 2019-12-06T20:33:06Z 2012 2012 Journal Article Ding, F., William, R., Wang, F., Liu, X.-W. (2012). Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation. Chemical Communications, 48(69), 8709-8711. https://hdl.handle.net/10356/101076 http://hdl.handle.net/10220/11099 10.1039/c2cc33641c en Chemical communications © 2012 The Royal Society of Chemistry.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description A highly efficient metal-free intermolecular C(sp3)–C(sp3) allyl–allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Ding, Feiqing
William, Ronny
Wang, Fei
Liu, Xue-Wei
format Article
author Ding, Feiqing
William, Ronny
Wang, Fei
Liu, Xue-Wei
spellingShingle Ding, Feiqing
William, Ronny
Wang, Fei
Liu, Xue-Wei
Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation
author_sort Ding, Feiqing
title Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation
title_short Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation
title_full Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation
title_fullStr Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation
title_full_unstemmed Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation
title_sort triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation
publishDate 2013
url https://hdl.handle.net/10356/101076
http://hdl.handle.net/10220/11099
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