Metal-mediated organic reactions in aqueous media
This thesis describes the indium(zinc)-copper promoted Barbier-type alkylation reactions of various nitrones with alkyl iodides in water; zinc-indium mediated pinacol coupling reaciton of aldehydes with α,β-unsaturated ketones in aqueous media; direct synthesis of alkyl indium reagents and their app...
Saved in:
| Main Author: | |
|---|---|
| Other Authors: | |
| Format: | Theses and Dissertations |
| Language: | English |
| Published: |
2012
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/47994 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Nanyang Technological University |
| Language: | English |
| Summary: | This thesis describes the indium(zinc)-copper promoted Barbier-type alkylation reactions of various nitrones with alkyl iodides in water; zinc-indium mediated pinacol coupling reaciton of aldehydes with α,β-unsaturated ketones in aqueous media; direct synthesis of alkyl indium reagents and their application in palladium-catalyzed coupling with aryl iodides; palladium catalyzed hydroboration of unactivated alkynes in water. |
|---|