New strategies for O- and C-glycosylation.

• المؤلف الرئيسي: Tan, Hong Yee.
• مؤلفون آخرون: Liu Xuewei
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2012
• الموضوعات: DRNTU::Science::Chemistry::Organic chemistry::Carbohydrates
• الوصول للمادة أونلاين: http://hdl.handle.net/10356/49504
• المؤسسة: Nanyang Technological University

In part A, we have established an efficient iron-catalyzed decarboxylative C-glycosylation of glycals with β-keto acids via decarboxylative Ferrier rearrangement strategy. This approach provides a wide range of β-keto-functionalized 2,3-unsaturated C-glycosides in moderate to good yields. Good α-sel...