New aspects of phosphirene chemistry

Two methodologies have been tested for the functionalization of phosphirenes. In the first one, the C−Si bond of a 2-silylphosphirene is activated by a substoichiometric quantity of fluoride ion (TBAF) in THF at −78 °C. Using this technique, it is possible to perform a protodesilylation or a functio...

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Bibliographic Details
Main Author: Panichakul, Duanghathai
Other Authors: Francois Mathey
Format: Theses and Dissertations
Language:English
Published: 2012
Subjects:
Online Access:https://hdl.handle.net/10356/49976
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Institution: Nanyang Technological University
Language: English