New aspects of phosphirene chemistry

• Main Author: Panichakul, Duanghathai
• Other Authors: Francois Mathey
• Format: Theses and Dissertations
• Language: English
• Published: 2012
• Subjects: DRNTU::Science::Chemistry
• Online Access: https://hdl.handle.net/10356/49976
• Institution: Nanyang Technological University

Two methodologies have been tested for the functionalization of phosphirenes. In the first one, the C−Si bond of a 2-silylphosphirene is activated by a substoichiometric quantity of fluoride ion (TBAF) in THF at −78 °C. Using this technique, it is possible to perform a protodesilylation or a functio...