Metal 1,3-Benzobis(thiophosphinoyl)methanediide complexes and a base-stabilized 2-silaallene derivative

• Main Author: Yang, Yifan
• Other Authors: School of Physical and Mathematical Sciences
• Format: Theses and Dissertations
• Language: English
• Published: 2013
• Subjects: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• Online Access: http://hdl.handle.net/10356/53520
• Institution: Nanyang Technological University

The syntheses of metal bis(thiophosphinoyl) and 1,3-benzobis(thiophosphinoyl)methanediide complexes are reported. The reaction of bis(thiophosphinoyl)methane [CH2(Ph2P=S)2] with 1 equivalent of KOtBu and 1.2 equivalent of nBuLi, followed by the hydrolysis to form the 1,3-benzobis(thiophosphinoyl)met...