Metal 1,3-Benzobis(thiophosphinoyl)methanediide complexes and a base-stabilized 2-silaallene derivative

The syntheses of metal bis(thiophosphinoyl) and 1,3-benzobis(thiophosphinoyl)methanediide complexes are reported. The reaction of bis(thiophosphinoyl)methane [CH2(Ph2P=S)2] with 1 equivalent of KOtBu and 1.2 equivalent of nBuLi, followed by the hydrolysis to form the 1,3-benzobis(thiophosphinoyl)met...

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Bibliographic Details
Main Author: Yang, Yifan
Other Authors: School of Physical and Mathematical Sciences
Format: Theses and Dissertations
Language:English
Published: 2013
Subjects:
Online Access:http://hdl.handle.net/10356/53520
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Institution: Nanyang Technological University
Language: English

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