Preparation of chiral EC(sp3)E’ phosphine-based mono- and di-nuclear palladium pincer complexes

• المؤلف الرئيسي: Tay, Wee Shan
• مؤلفون آخرون: Leung Pak Hing
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2016
• الموضوعات: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• الوصول للمادة أونلاين: http://hdl.handle.net/10356/67020
• المؤسسة: Nanyang Technological University

Ten enantiopure Pd pincer complexes with aliphatic and unsymmetrical characteristics have been synthesized efficiently. Chirality on the ligand backbone was introduced via an asymmetric H-P bond addition reaction by two structurally-dissimilar catalysts with >99% ee’s. Challenging C(sp3)-H bond a...