The application of diazo oxime ethers in the synthesis of heterocycles

• Main Author: Qi, Xinxin
• Other Authors: School of Physical and Mathematical Sciences
• Format: Theses and Dissertations
• Language: English
• Published: 2013
• Subjects: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• Online Access: http://hdl.handle.net/10356/54741
• Institution: Nanyang Technological University

In this thesis, we have investigated the reactivities of diazo oxime ethers and their applications in the synthesis of various heterocycles. As a result, 2-isoxazolines and 2H-azirines have been prepared from α-oximino diazo compounds with Rh2(Piv)4 under mild reaction conditions. Furthermor...