Chemistry of base-stabilized group 14 element (I) dimers
This thesis describes the reactivity studies of an amidinate-stabilized silicon(I) dimer [LSi:-Si:L] (L = PhC(NtBu)2). The synthesis, characterization and theoretical studies of the first examples of heavier group 14 cyclobutadiene analogues which comprise of heavier group 14 elements, silicon, germ...
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sg-ntu-dr.10356-552962023-02-28T23:33:08Z Chemistry of base-stabilized group 14 element (I) dimers Yeong, Crystal Huixian So Cheuk Wai School of Physical and Mathematical Sciences DRNTU::Science::Chemistry This thesis describes the reactivity studies of an amidinate-stabilized silicon(I) dimer [LSi:-Si:L] (L = PhC(NtBu)2). The synthesis, characterization and theoretical studies of the first examples of heavier group 14 cyclobutadiene analogues which comprise of heavier group 14 elements, silicon, germanium and tin, in the four-membered skeleton are also described. Additionally, the synthesis and reactivity of an amidinate-stabilized silyliumylidene cation [LSi(DMAP)]OTf is described. Lastly, the synthesis and characterization of a germanium(I) dimer and a germylidenide anion stabilized by the 2-imino-5,6-methylenedioxylphenyl ligand is described. DOCTOR OF PHILOSOPHY (SPMS) 2014-01-28T08:47:35Z 2014-01-28T08:47:35Z 2014 2014 Thesis Yeong, C. H. (2014). Chemistry of base-stabilized group 14 element(I) dimers. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/55296 10.32657/10356/55296 en 155 p. application/pdf |
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DRNTU::Science::Chemistry Yeong, Crystal Huixian Chemistry of base-stabilized group 14 element (I) dimers |
| description |
This thesis describes the reactivity studies of an amidinate-stabilized silicon(I) dimer [LSi:-Si:L] (L = PhC(NtBu)2). The synthesis, characterization and theoretical studies of the first examples of heavier group 14 cyclobutadiene analogues which comprise of heavier group 14 elements, silicon, germanium and tin, in the four-membered skeleton are also described. Additionally, the synthesis and reactivity of an amidinate-stabilized silyliumylidene cation [LSi(DMAP)]OTf is described. Lastly, the synthesis and characterization of a germanium(I) dimer and a germylidenide anion stabilized by the 2-imino-5,6-methylenedioxylphenyl ligand is described. |
| author2 |
So Cheuk Wai |
| author_facet |
So Cheuk Wai Yeong, Crystal Huixian |
| format |
Theses and Dissertations |
| author |
Yeong, Crystal Huixian |
| author_sort |
Yeong, Crystal Huixian |
| title |
Chemistry of base-stabilized group 14 element (I) dimers |
| title_short |
Chemistry of base-stabilized group 14 element (I) dimers |
| title_full |
Chemistry of base-stabilized group 14 element (I) dimers |
| title_fullStr |
Chemistry of base-stabilized group 14 element (I) dimers |
| title_full_unstemmed |
Chemistry of base-stabilized group 14 element (I) dimers |
| title_sort |
chemistry of base-stabilized group 14 element (i) dimers |
| publishDate |
2014 |
| url |
https://hdl.handle.net/10356/55296 |
| _version_ |
1759853289784999936 |