Part I: Desymmetrization of cyclic olefins via asymmetric Heck reaction and hydroarylation. Part II: Fast Suzuki coupling of aryl tosylates
Part 1. Asymmetric Heck reaction of substituted cyclopentenes gave one stereoisomer in excellent enantio- and diastereoselectivities. The high selectivity as unprecedented in Heck reaction. (R)-Xyl-SDP(O) was uniquely effective as chiral ligand. Various aryl triflates can be used. The same catalyst...
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| Format: | Theses and Dissertations |
| Language: | English |
| Published: |
2014
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| Online Access: | https://hdl.handle.net/10356/55382 |
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| Institution: | Nanyang Technological University |
| Language: | English |