Part I: transition metal complexes with nitrone-based bidentate and tridentate ligands: synthesis, structural characterizations, and catalysis. Part II: N-heterocyclic carbene based ruthenium catalysts for direct amide synthesis from alcohols and amines.

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Bibliographic Details
Main Author:	Zhang, Yao
Other Authors:	Hong Soon Hyeok
Format:	Theses and Dissertations
Published:	2014
Subjects:	DRNTU::Science::Chemistry::Physical chemistry::Catalysis
Online Access:	http://hdl.handle.net/10356/57395
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Institution:	Nanyang Technological University

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spelling	sg-ntu-dr.10356-573952023-02-28T23:36:37Z Part I: transition metal complexes with nitrone-based bidentate and tridentate ligands: synthesis, structural characterizations, and catalysis. Part II: N-heterocyclic carbene based ruthenium catalysts for direct amide synthesis from alcohols and amines. Zhang, Yao Hong Soon Hyeok School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Physical chemistry::Catalysis 145 p. This thesis is divided into two parts. In part one, several nitrone-based bidentate and tridentate ligands have been developed, and the subsequent metalations of these ligands allowed us to synthesize a series of neutral and/or cationic Pd (II), Ni (II) and Ru (II) OXO-type (X = C or N) pincer complexes and cationic Ir (III) complexes. The structural characterizations and catalytic abilities of these complexes in C-C couplings, transfer hydrogenation reaction, and Oppenauer-type oxidation of alcohol were studied thoroughly. In part two, iV-heterocyclic carbene based ruthenium complexes were developed as highly active catalysts for direct amide synthesis from alcohols and amines. The well-defined catalysts provided mechanistic insight suggesting a ruthenium hydride species as an active catalytic intermediate. Doctor of Philosophy (SPMS) 2014-04-07T10:21:52Z 2014-04-07T10:21:52Z 2011 2011 Thesis http://hdl.handle.net/10356/57395 Nanyang Technological University application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
topic	DRNTU::Science::Chemistry::Physical chemistry::Catalysis
spellingShingle	DRNTU::Science::Chemistry::Physical chemistry::Catalysis Zhang, Yao Part I: transition metal complexes with nitrone-based bidentate and tridentate ligands: synthesis, structural characterizations, and catalysis. Part II: N-heterocyclic carbene based ruthenium catalysts for direct amide synthesis from alcohols and amines.
description	145 p.
author2	Hong Soon Hyeok
author_facet	Hong Soon Hyeok Zhang, Yao
format	Theses and Dissertations
author	Zhang, Yao
author_sort	Zhang, Yao
title	Part I: transition metal complexes with nitrone-based bidentate and tridentate ligands: synthesis, structural characterizations, and catalysis. Part II: N-heterocyclic carbene based ruthenium catalysts for direct amide synthesis from alcohols and amines.
title_short	Part I: transition metal complexes with nitrone-based bidentate and tridentate ligands: synthesis, structural characterizations, and catalysis. Part II: N-heterocyclic carbene based ruthenium catalysts for direct amide synthesis from alcohols and amines.
title_full	Part I: transition metal complexes with nitrone-based bidentate and tridentate ligands: synthesis, structural characterizations, and catalysis. Part II: N-heterocyclic carbene based ruthenium catalysts for direct amide synthesis from alcohols and amines.
title_fullStr	Part I: transition metal complexes with nitrone-based bidentate and tridentate ligands: synthesis, structural characterizations, and catalysis. Part II: N-heterocyclic carbene based ruthenium catalysts for direct amide synthesis from alcohols and amines.
title_full_unstemmed	Part I: transition metal complexes with nitrone-based bidentate and tridentate ligands: synthesis, structural characterizations, and catalysis. Part II: N-heterocyclic carbene based ruthenium catalysts for direct amide synthesis from alcohols and amines.
title_sort	part i: transition metal complexes with nitrone-based bidentate and tridentate ligands: synthesis, structural characterizations, and catalysis. part ii: n-heterocyclic carbene based ruthenium catalysts for direct amide synthesis from alcohols and amines.
publishDate	2014
url	http://hdl.handle.net/10356/57395
_version_	1759853976891686912

Part I: transition metal complexes with nitrone-based bidentate and tridentate ligands: synthesis, structural characterizations, and catalysis. Part II: N-heterocyclic carbene based ruthenium catalysts for direct amide synthesis from alcohols and amines.

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