Design, syntheses and applications of chiral transition metal complexes bearing phosphorus-containing ligands

• Main Author: Yang, Xiangyuan
• Other Authors: Leung Pak Hing
• Format: Theses and Dissertations
• Language: English
• Published: 2015
• Subjects: DRNTU::Science::Chemistry::Analytical chemistry
• Online Access: https://hdl.handle.net/10356/65840
• Institution: Nanyang Technological University

A series of optically active tertiary phosphine compounds were prepared via catalytic asymmetric hydrophosphination of specially designed substrates. The C-stereogenic phosphines obtained were used in the formation of symmetrical PC(aryl)P, unsymmetrical PC(aryl)N and NC(sp3)X (X = O, S) transition...