Design, syntheses and applications of chiral transition metal complexes bearing phosphorus-containing ligands

• المؤلف الرئيسي: Yang, Xiangyuan
• مؤلفون آخرون: Leung Pak Hing
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2015
• الموضوعات: DRNTU::Science::Chemistry::Analytical chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/65840
• المؤسسة: Nanyang Technological University

A series of optically active tertiary phosphine compounds were prepared via catalytic asymmetric hydrophosphination of specially designed substrates. The C-stereogenic phosphines obtained were used in the formation of symmetrical PC(aryl)P, unsymmetrical PC(aryl)N and NC(sp3)X (X = O, S) transition...