Preparation of chiral EC(sp3)E’ phosphine-based mono- and di-nuclear palladium pincer complexes

• 主要作者: Tay, Wee Shan
• 其他作者: Leung Pak Hing
• 格式: Theses and Dissertations
• 語言: English
• 出版: 2016
• 主題: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• 在線閱讀: http://hdl.handle.net/10356/67020

Ten enantiopure Pd pincer complexes with aliphatic and unsymmetrical characteristics have been synthesized efficiently. Chirality on the ligand backbone was introduced via an asymmetric H-P bond addition reaction by two structurally-dissimilar catalysts with >99% ee’s. Challenging C(sp3)-H bond a...