Synthesis and reactivities of novel divalent group 14 elements species

• Main Author: Wang, Liliang
• Other Authors: Kinjo Rei
• Format: Theses and Dissertations
• Language: English
• Published: 2018
• Subjects: DRNTU::Science::Chemistry::Organic chemistry
• Online Access: http://hdl.handle.net/10356/73513
• Institution: Nanyang Technological University

In this thesis, we have first synthesized a cyclic (alkyl)(amino) germylene (CAAGe) which possesses the high-lying HOMO−1 and low-lying LUMO, which was supported by DFT calculations. The reactivities have been investigated subsequently. The reaction of CAAGe with S8 was first carried out, where led...