Synthesis and reactivities of novel divalent group 14 elements species

• 主要作者: Wang, Liliang
• 其他作者: Kinjo Rei
• 格式: Theses and Dissertations
• 語言: English
• 出版: 2018
• 主題: DRNTU::Science::Chemistry::Organic chemistry
• 在線閱讀: http://hdl.handle.net/10356/73513

In this thesis, we have first synthesized a cyclic (alkyl)(amino) germylene (CAAGe) which possesses the high-lying HOMO−1 and low-lying LUMO, which was supported by DFT calculations. The reactivities have been investigated subsequently. The reaction of CAAGe with S8 was first carried out, where led...