Effect of Lanthanum Doping on Modulating Thermochromic Properties of VO2 Thin Films
Lanthanum (La) doped vanadium dioxide (VO2) thin films were fabricated through a facile sol-gel technique. The La doping was found to be effective in reducing the phase transition temperature (τc) of VO2 below the 4 at.% doping level, with a reducing rate of -1.1 °C/at.%. In addition, below the 3 at...
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sg-ntu-dr.10356-805252023-03-04T17:13:20Z Effect of Lanthanum Doping on Modulating Thermochromic Properties of VO2 Thin Films Wang, Ning Shun, Nigel Tan Chew Duchamp, Martial Dunin-Borkowski, Rafal E. Li, Zhong Long, Yi School of Materials Science & Engineering School of Mechanical and Aerospace Engineering Thin films Lanthanum (La) doped vanadium dioxide (VO2) thin films were fabricated through a facile sol-gel technique. The La doping was found to be effective in reducing the phase transition temperature (τc) of VO2 below the 4 at.% doping level, with a reducing rate of -1.1 °C/at.%. In addition, below the 3 at.% La doping level, the band gap (Eg) decreased steadily with the increasing addition of La dopants. The 5 at.% La doping can enhance both integrated visible transmission (Tlum) and solar modulating ability (ΔTsol) simultaneously. The combination of Tlum=50.1% and ΔTsol=10.3% represents the best value for VO2 continuous thin films. NRF (Natl Research Foundation, S’pore) MOE (Min. of Education, S’pore) Accepted Version 2016-06-03T07:02:50Z 2019-12-06T13:51:28Z 2016-06-03T07:02:50Z 2019-12-06T13:51:28Z 2016 2016 Journal Article Wang, N., Shun, N. T. C., Duchamp, M., Dunin-Borkowski, R. E., Li, Z., & Long, Y. (2016). Effect of Lanthanum Doping on Modulating Thermochromic Properties of VO2 Thin Films. RSC Advances, 6, 48455-48461. https://hdl.handle.net/10356/80525 http://hdl.handle.net/10220/40611 10.1039/C6RA09514C 192528 en RSC Advances © 2016 The Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by RSC Advances, The Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1039/C6RA09514C]. application/pdf |
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Lanthanum (La) doped vanadium dioxide (VO2) thin films were fabricated through a facile sol-gel technique. The La doping was found to be effective in reducing the phase transition temperature (τc) of VO2 below the 4 at.% doping level, with a reducing rate of -1.1 °C/at.%. In addition, below the 3 at.% La doping level, the band gap (Eg) decreased steadily with the increasing addition of La dopants. The 5 at.% La doping can enhance both integrated visible transmission (Tlum) and solar modulating ability (ΔTsol) simultaneously. The combination of Tlum=50.1% and ΔTsol=10.3% represents the best value for VO2 continuous thin films. |
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School of Materials Science & Engineering |
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School of Materials Science & Engineering Wang, Ning Shun, Nigel Tan Chew Duchamp, Martial Dunin-Borkowski, Rafal E. Li, Zhong Long, Yi |
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Article |
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Wang, Ning Shun, Nigel Tan Chew Duchamp, Martial Dunin-Borkowski, Rafal E. Li, Zhong Long, Yi |
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Wang, Ning |
title |
Effect of Lanthanum Doping on Modulating Thermochromic Properties of VO2 Thin Films |
title_short |
Effect of Lanthanum Doping on Modulating Thermochromic Properties of VO2 Thin Films |
title_full |
Effect of Lanthanum Doping on Modulating Thermochromic Properties of VO2 Thin Films |
title_fullStr |
Effect of Lanthanum Doping on Modulating Thermochromic Properties of VO2 Thin Films |
title_full_unstemmed |
Effect of Lanthanum Doping on Modulating Thermochromic Properties of VO2 Thin Films |
title_sort |
effect of lanthanum doping on modulating thermochromic properties of vo2 thin films |
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2016 |
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https://hdl.handle.net/10356/80525 http://hdl.handle.net/10220/40611 |
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