Copper-mediated oxidative trifluoromethylthiolation of potassium aryltrifluoroborates with elemental sulfur and Ruppert-Prakash reagent

A facile procedure for the copper-mediated oxidative trifluoromethylthiolation of potassium aryl- and heteroaryltrifluoroborates with Ruppert–Prakash reagent and elemental sulfur is presented. Aryl trifluoromethyl thioethers can be prepared in good to moderate yield under mild reaction conditions.

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Main Authors:	Srinivas Reddy Dubbaka, Azmi Reddy Atthunuri, Koraboina Chandra Prakash, Prabhu Rangabashyam, Satyanarayana Gadde, Rajesh Kothandaraman
Other Authors:	School of Chemical and Biomedical Engineering
Format:	Article
Language:	English
Published:	2016
Subjects:	potassium aryltrifluoroborates copper Ruppert–Prakash reagent elemental sulfur aryl trifluoromethyl thioethers trifluoromethylthiolation
Online Access:	https://hdl.handle.net/10356/80795 http://hdl.handle.net/10220/40627
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Institution:	Nanyang Technological University
Language:	English

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spelling	sg-ntu-dr.10356-807952023-12-29T06:48:09Z Copper-mediated oxidative trifluoromethylthiolation of potassium aryltrifluoroborates with elemental sulfur and Ruppert-Prakash reagent Srinivas Reddy Dubbaka Azmi Reddy Atthunuri Koraboina Chandra Prakash Prabhu Rangabashyam Satyanarayana Gadde Rajesh Kothandaraman School of Chemical and Biomedical Engineering potassium aryltrifluoroborates copper Ruppert–Prakash reagent elemental sulfur aryl trifluoromethyl thioethers trifluoromethylthiolation A facile procedure for the copper-mediated oxidative trifluoromethylthiolation of potassium aryl- and heteroaryltrifluoroborates with Ruppert–Prakash reagent and elemental sulfur is presented. Aryl trifluoromethyl thioethers can be prepared in good to moderate yield under mild reaction conditions. Accepted version 2016-06-07T06:47:20Z 2019-12-06T13:59:06Z 2016-06-07T06:47:20Z 2019-12-06T13:59:06Z 2016 2016 Journal Article Srinivas Reddy Dubbaka, Azmi Reddy Atthunuri, Koraboina Chandra Prakash, Prabhu Rangabashyam, Satyanarayana Gadde, Rajesh Kothandaraman. (2016). Copper-Mediated Oxidative Trifluoromethylthiolation of Potassium Aryltrifluoroborates with Elemental Sulfur and Ruppert–Prakash Reagent. Synthesis, 48(8), 1246-1252. 0039-7881 https://hdl.handle.net/10356/80795 http://hdl.handle.net/10220/40627 10.1055/s-0035-1561565 193856 en Synthesis © 2016 Georg Thieme Verlag Stuttgart. This is the author created version of a work that has been peer reviewed and accepted for publication in Synthesis, published by Thieme Publishing on behalf of Georg Thieme Verlag Stuttgart. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1055/s-0035-1561565]. 7 p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	potassium aryltrifluoroborates copper Ruppert–Prakash reagent elemental sulfur aryl trifluoromethyl thioethers trifluoromethylthiolation
spellingShingle	potassium aryltrifluoroborates copper Ruppert–Prakash reagent elemental sulfur aryl trifluoromethyl thioethers trifluoromethylthiolation Srinivas Reddy Dubbaka Azmi Reddy Atthunuri Koraboina Chandra Prakash Prabhu Rangabashyam Satyanarayana Gadde Rajesh Kothandaraman Copper-mediated oxidative trifluoromethylthiolation of potassium aryltrifluoroborates with elemental sulfur and Ruppert-Prakash reagent
description	A facile procedure for the copper-mediated oxidative trifluoromethylthiolation of potassium aryl- and heteroaryltrifluoroborates with Ruppert–Prakash reagent and elemental sulfur is presented. Aryl trifluoromethyl thioethers can be prepared in good to moderate yield under mild reaction conditions.
author2	School of Chemical and Biomedical Engineering
author_facet	School of Chemical and Biomedical Engineering Srinivas Reddy Dubbaka Azmi Reddy Atthunuri Koraboina Chandra Prakash Prabhu Rangabashyam Satyanarayana Gadde Rajesh Kothandaraman
format	Article
author	Srinivas Reddy Dubbaka Azmi Reddy Atthunuri Koraboina Chandra Prakash Prabhu Rangabashyam Satyanarayana Gadde Rajesh Kothandaraman
author_sort	Srinivas Reddy Dubbaka
title	Copper-mediated oxidative trifluoromethylthiolation of potassium aryltrifluoroborates with elemental sulfur and Ruppert-Prakash reagent
title_short	Copper-mediated oxidative trifluoromethylthiolation of potassium aryltrifluoroborates with elemental sulfur and Ruppert-Prakash reagent
title_full	Copper-mediated oxidative trifluoromethylthiolation of potassium aryltrifluoroborates with elemental sulfur and Ruppert-Prakash reagent
title_fullStr	Copper-mediated oxidative trifluoromethylthiolation of potassium aryltrifluoroborates with elemental sulfur and Ruppert-Prakash reagent
title_full_unstemmed	Copper-mediated oxidative trifluoromethylthiolation of potassium aryltrifluoroborates with elemental sulfur and Ruppert-Prakash reagent
title_sort	copper-mediated oxidative trifluoromethylthiolation of potassium aryltrifluoroborates with elemental sulfur and ruppert-prakash reagent
publishDate	2016
url	https://hdl.handle.net/10356/80795 http://hdl.handle.net/10220/40627
_version_	1787136567565877248

Copper-mediated oxidative trifluoromethylthiolation of potassium aryltrifluoroborates with elemental sulfur and Ruppert-Prakash reagent

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