Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions

• المؤلفون الرئيسيون: Lei, Chuanhu, Yip, Yong Jie, Zhou, Jianrong Steve
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2017
• الموضوعات: Aryl Olefins; Ketone
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/86882; http://hdl.handle.net/10220/44198
• المؤسسة: Nanyang Technological University

Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins directly. The neutral condition allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated.