Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions

Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions

Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins directly. The neutral condition allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated.

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Bibliographic Details
Main Authors: Lei, Chuanhu, Yip, Yong Jie, Zhou, Jianrong Steve
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2017
Subjects:
Aryl Olefins
Ketone
Online Access:https://hdl.handle.net/10356/86882
http://hdl.handle.net/10220/44198
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-868822023-02-28T19:23:40Z Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions Lei, Chuanhu Yip, Yong Jie Zhou, Jianrong Steve School of Physical and Mathematical Sciences Aryl Olefins Ketone Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins directly. The neutral condition allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated. MOE (Min. of Education, S’pore) Accepted version 2017-12-27T04:25:31Z 2019-12-06T16:30:52Z 2017-12-27T04:25:31Z 2019-12-06T16:30:52Z 2017 Journal Article Lei, C., Yip, Y. J., & Zhou, J. S. (2017). Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions. Journal of the American Chemical Society, 139(17), 6086-6089. 0002-7863 https://hdl.handle.net/10356/86882 http://hdl.handle.net/10220/44198 10.1021/jacs.7b02742 en Journal of the American Chemical Society © 2017 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of the American Chemical Society, ACS Publications. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/jacs.7b02742]. 6 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Aryl Olefins
Ketone
spellingShingle Aryl Olefins
Ketone
Lei, Chuanhu
Yip, Yong Jie
Zhou, Jianrong Steve
Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions
description Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins directly. The neutral condition allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Lei, Chuanhu
Yip, Yong Jie
Zhou, Jianrong Steve
format Article
author Lei, Chuanhu
Yip, Yong Jie
Zhou, Jianrong Steve
author_sort Lei, Chuanhu
title Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions
title_short Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions
title_full Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions
title_fullStr Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions
title_full_unstemmed Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions
title_sort nickel-catalyzed direct synthesis of aryl olefins from ketones and organoboron reagents under neutral conditions
publishDate 2017
url https://hdl.handle.net/10356/86882
http://hdl.handle.net/10220/44198
_version_ 1759853730788802560

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