Copper-catalyzed aerobic radical C-C bond cleavage of N-H ketimines

• المؤلفون الرئيسيون: Tnay, Ya Lin, Ang, Gim Yean, Chiba, Shunsuke
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2016
• الموضوعات: copper; ketimines; molecular oxygen; radical; C-C bond cleavage
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/81491; http://hdl.handle.net/10220/40822

We report herein studies on copper-catalyzed aerobic radical C-C bond cleavage of N-H ketimines. Treatment of N-H ketimines having an alpha-sp3 hybridized carbon under Cu-catalyzed aerobic reaction conditions resulted in a radical fragmentation with C-C bond cleavage to give the corresponding carbon...