Rhenium carbonyl complexes with monodentate-coordinated diphosphines
The amine oxide-assisted decarbonylation of [Re2(CO)10] followed by reaction with excess diphosphine produces the monodentate-coordinated diphosphine complexes [Re2(CO)9(?1-P-P)] and the open-bridge dimers [{Re2(CO)9}2(µ-P-P)] [P-P = Ph2P(CH2)nPPh2, n = 1-6; trans-1,2-bis(diphenylphosphino)ethylene...
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| Format: | Theses and Dissertations |
| Published: |
2008
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| Online Access: | http://hdl.handle.net/10356/8173 |
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| Institution: | Nanyang Technological University |
| Summary: | The amine oxide-assisted decarbonylation of [Re2(CO)10] followed by reaction with excess diphosphine produces the monodentate-coordinated diphosphine complexes [Re2(CO)9(?1-P-P)] and the open-bridge dimers [{Re2(CO)9}2(µ-P-P)] [P-P = Ph2P(CH2)nPPh2, n = 1-6; trans-1,2-bis(diphenylphosphino)ethylene (dppet) and 1-di(o-anisyl)phosphino-3-diphenylphosphinopropane(dadpp)]. |
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