Rhenium carbonyl complexes with monodentate-coordinated diphosphines
The amine oxide-assisted decarbonylation of [Re2(CO)10] followed by reaction with excess diphosphine produces the monodentate-coordinated diphosphine complexes [Re2(CO)9(?1-P-P)] and the open-bridge dimers [{Re2(CO)9}2(µ-P-P)] [P-P = Ph2P(CH2)nPPh2, n = 1-6; trans-1,2-bis(diphenylphosphino)ethylene...
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2008
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sg-ntu-dr.10356-81732019-12-10T14:11:37Z Rhenium carbonyl complexes with monodentate-coordinated diphosphines Fan, Wei Yan, Yaw Kai School of Applied Science DRNTU::Science::Chemistry The amine oxide-assisted decarbonylation of [Re2(CO)10] followed by reaction with excess diphosphine produces the monodentate-coordinated diphosphine complexes [Re2(CO)9(?1-P-P)] and the open-bridge dimers [{Re2(CO)9}2(µ-P-P)] [P-P = Ph2P(CH2)nPPh2, n = 1-6; trans-1,2-bis(diphenylphosphino)ethylene (dppet) and 1-di(o-anisyl)phosphino-3-diphenylphosphinopropane(dadpp)]. Master of Science 2008-09-23T09:23:25Z 2008-09-23T09:23:25Z 1999 1999 Thesis http://hdl.handle.net/10356/8173 Nanyang Technological University application/pdf |
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DRNTU::Science::Chemistry |
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DRNTU::Science::Chemistry Fan, Wei Rhenium carbonyl complexes with monodentate-coordinated diphosphines |
| description |
The amine oxide-assisted decarbonylation of [Re2(CO)10] followed by reaction with excess diphosphine produces the monodentate-coordinated diphosphine complexes [Re2(CO)9(?1-P-P)] and the open-bridge dimers [{Re2(CO)9}2(µ-P-P)] [P-P = Ph2P(CH2)nPPh2, n = 1-6; trans-1,2-bis(diphenylphosphino)ethylene (dppet) and 1-di(o-anisyl)phosphino-3-diphenylphosphinopropane(dadpp)]. |
| author2 |
Yan, Yaw Kai |
| author_facet |
Yan, Yaw Kai Fan, Wei |
| format |
Theses and Dissertations |
| author |
Fan, Wei |
| author_sort |
Fan, Wei |
| title |
Rhenium carbonyl complexes with monodentate-coordinated diphosphines |
| title_short |
Rhenium carbonyl complexes with monodentate-coordinated diphosphines |
| title_full |
Rhenium carbonyl complexes with monodentate-coordinated diphosphines |
| title_fullStr |
Rhenium carbonyl complexes with monodentate-coordinated diphosphines |
| title_full_unstemmed |
Rhenium carbonyl complexes with monodentate-coordinated diphosphines |
| title_sort |
rhenium carbonyl complexes with monodentate-coordinated diphosphines |
| publishDate |
2008 |
| url |
http://hdl.handle.net/10356/8173 |
| _version_ |
1681040898662596608 |