Trimerization of enones under air enabled by NHC/NaOtBu via a SET radical pathway
An unusual trimerization of enone via a formal [2 + 2 + 2] process is disclosed. The reaction is initiated by a radical process enabled by NaOtBu and N-heterocyclic carbene (NHC). Molecular oxygen (air) is involved in key steps of the radical intermediate formation and carbon–carbon bond cleavage in...
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Main Authors: | , , , , , , , |
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Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2017
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/81973 http://hdl.handle.net/10220/42449 |
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Institution: | Nanyang Technological University |
Language: | English |
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