Fifth-Order Three-Dimensional Electronic Spectroscopy Using a Pump–Probe Configuration
We present the theoretical details and experimental demonstration of fifth-order three-dimensional (3D) electronic spectroscopy using a pump–probe beam geometry. This is achieved using a pulse shaper and appropriate phase cycling schemes. We show how 8-step and 27-step phase cycling schemes can meas...
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sg-ntu-dr.10356-822402023-02-28T19:35:46Z Fifth-Order Three-Dimensional Electronic Spectroscopy Using a Pump–Probe Configuration Zhang, Zhengyang Wells, Kym L. Seidel, Marco T. Tan, Howe-Siang School of Physical and Mathematical Sciences Chemistry and Biological Chemistry We present the theoretical details and experimental demonstration of fifth-order three-dimensional (3D) electronic spectroscopy using a pump–probe beam geometry. This is achieved using a pulse shaper and appropriate phase cycling schemes. We show how 8-step and 27-step phase cycling schemes can measure purely absorptive 3D spectra as well as 3D spectra for the individual fifth-order processes that contribute to the purely absorptive spectrum. 3D spectra as a function of two separate controllable waiting time periods can be obtained. The peak shapes and positions of the peaks in the experimental measurement correspond well to theory. NRF (Natl Research Foundation, S’pore) ASTAR (Agency for Sci., Tech. and Research, S’pore) Accepted version 2016-01-29T06:34:09Z 2019-12-06T14:51:32Z 2016-01-29T06:34:09Z 2019-12-06T14:51:32Z 2013 Journal Article Zhang, Z., Wells, K. L., Seidel, M. T., & Tan, H.-S. (2013). Fifth-Order Three-Dimensional Electronic Spectroscopy Using a Pump–Probe Configuration. The Journal of Physical Chemistry B, 117(49), 15369-15385. 1520-6106 https://hdl.handle.net/10356/82240 http://hdl.handle.net/10220/39845 10.1021/jp4046403 en The Journal of Physical Chemistry B © 2013 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by The Journal of Physical Chemistry B, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/jp4046403]. 53 p. application/pdf |
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Nanyang Technological University |
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Chemistry and Biological Chemistry |
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Chemistry and Biological Chemistry Zhang, Zhengyang Wells, Kym L. Seidel, Marco T. Tan, Howe-Siang Fifth-Order Three-Dimensional Electronic Spectroscopy Using a Pump–Probe Configuration |
| description |
We present the theoretical details and experimental demonstration of fifth-order three-dimensional (3D) electronic spectroscopy using a pump–probe beam geometry. This is achieved using a pulse shaper and appropriate phase cycling schemes. We show how 8-step and 27-step phase cycling schemes can measure purely absorptive 3D spectra as well as 3D spectra for the individual fifth-order processes that contribute to the purely absorptive spectrum. 3D spectra as a function of two separate controllable waiting time periods can be obtained. The peak shapes and positions of the peaks in the experimental measurement correspond well to theory. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Zhang, Zhengyang Wells, Kym L. Seidel, Marco T. Tan, Howe-Siang |
| format |
Article |
| author |
Zhang, Zhengyang Wells, Kym L. Seidel, Marco T. Tan, Howe-Siang |
| author_sort |
Zhang, Zhengyang |
| title |
Fifth-Order Three-Dimensional Electronic Spectroscopy Using a Pump–Probe Configuration |
| title_short |
Fifth-Order Three-Dimensional Electronic Spectroscopy Using a Pump–Probe Configuration |
| title_full |
Fifth-Order Three-Dimensional Electronic Spectroscopy Using a Pump–Probe Configuration |
| title_fullStr |
Fifth-Order Three-Dimensional Electronic Spectroscopy Using a Pump–Probe Configuration |
| title_full_unstemmed |
Fifth-Order Three-Dimensional Electronic Spectroscopy Using a Pump–Probe Configuration |
| title_sort |
fifth-order three-dimensional electronic spectroscopy using a pump–probe configuration |
| publishDate |
2016 |
| url |
https://hdl.handle.net/10356/82240 http://hdl.handle.net/10220/39845 |
| _version_ |
1759856164601856000 |