Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins

Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins

Asymmetric transfer hydrogenation of electron-deficient olefins is realized with nickel catalysts supported by strongly σ-donating bisphosphines. Deuterium labeling experiments point to a reaction sequence of formate decarboxylation, asymmetric hydride insertion and non-stereoselective protonation o...

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Main Authors: Guo, Siyu, Yang, Peng, Zhou, Jianrong Steve
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2016
Subjects:
Chemistry and Biological Chemistry
Online Access:https://hdl.handle.net/10356/82663
http://hdl.handle.net/10220/40239
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-826632023-02-28T19:29:01Z Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins Guo, Siyu Yang, Peng Zhou, Jianrong Steve School of Physical and Mathematical Sciences Chemistry and Biological Chemistry Asymmetric transfer hydrogenation of electron-deficient olefins is realized with nickel catalysts supported by strongly σ-donating bisphosphines. Deuterium labeling experiments point to a reaction sequence of formate decarboxylation, asymmetric hydride insertion and non-stereoselective protonation of resulting nickel enolates. Published version 2016-03-10T04:04:41Z 2019-12-06T14:59:55Z 2016-03-10T04:04:41Z 2019-12-06T14:59:55Z 2015 Journal Article Guo, S., Yang, P., & Zhou, J. S. (2015). Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins. Chemical Communications, 51(60), 12115-12117. 1359-7345 https://hdl.handle.net/10356/82663 http://hdl.handle.net/10220/40239 10.1039/C5CC01632K en Chemical Communications This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. 3 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Chemistry and Biological Chemistry
spellingShingle Chemistry and Biological Chemistry
Guo, Siyu
Yang, Peng
Zhou, Jianrong Steve
Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins
description Asymmetric transfer hydrogenation of electron-deficient olefins is realized with nickel catalysts supported by strongly σ-donating bisphosphines. Deuterium labeling experiments point to a reaction sequence of formate decarboxylation, asymmetric hydride insertion and non-stereoselective protonation of resulting nickel enolates.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Guo, Siyu
Yang, Peng
Zhou, Jianrong Steve
format Article
author Guo, Siyu
Yang, Peng
Zhou, Jianrong Steve
author_sort Guo, Siyu
title Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins
title_short Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins
title_full Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins
title_fullStr Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins
title_full_unstemmed Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins
title_sort nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins
publishDate 2016
url https://hdl.handle.net/10356/82663
http://hdl.handle.net/10220/40239
_version_ 1759857334589325312

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