Pummerer Reaction of Sulfoxides in Acetic Anhydride Catalyzed by Al-MCM-41

Pummerer Reaction of Sulfoxides in Acetic Anhydride Catalyzed by Al-MCM-41

The Pummerer reaction of acetic anhydride with both alkyl aryl sulfoxides and dialkyl sulfoxides was efficiently promoted by a mesoporous aluminosilicate Al-MCM-41 to afford the corresponding α-acetoxy sulfides in high yields. The catalyst was easily recovered by filtration and could be reused three...

Full description

Saved in:
Bibliographic Details
Main Authors: Ito, Suguru, Kubota, Yoshihiro, Asami, Masatoshi
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2016
Subjects:
Chemistry and Biological Chemistry
Online Access:https://hdl.handle.net/10356/82874
http://hdl.handle.net/10220/40364
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
id sg-ntu-dr.10356-82874
record_format dspace
spelling sg-ntu-dr.10356-828742020-03-07T12:31:26Z Pummerer Reaction of Sulfoxides in Acetic Anhydride Catalyzed by Al-MCM-41 Ito, Suguru Kubota, Yoshihiro Asami, Masatoshi School of Physical and Mathematical Sciences Chemistry and Biological Chemistry The Pummerer reaction of acetic anhydride with both alkyl aryl sulfoxides and dialkyl sulfoxides was efficiently promoted by a mesoporous aluminosilicate Al-MCM-41 to afford the corresponding α-acetoxy sulfides in high yields. The catalyst was easily recovered by filtration and could be reused three times without a significant loss of catalytic activity. 2016-04-01T02:24:07Z 2019-12-06T15:07:22Z 2016-04-01T02:24:07Z 2019-12-06T15:07:22Z 2015 Journal Article Ito, S., Kubota, Y., & Asami, M. (2016). Pummerer Reaction of Sulfoxides in Acetic Anhydride Catalyzed by Al-MCM-41. Chemistry Letters, 45(1), 16-18. 0366-7022 https://hdl.handle.net/10356/82874 http://hdl.handle.net/10220/40364 10.1246/cl.150896 en Chemistry Letters © 2016 Chemical Society of Japan.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic Chemistry and Biological Chemistry
spellingShingle Chemistry and Biological Chemistry
Ito, Suguru
Kubota, Yoshihiro
Asami, Masatoshi
Pummerer Reaction of Sulfoxides in Acetic Anhydride Catalyzed by Al-MCM-41
description The Pummerer reaction of acetic anhydride with both alkyl aryl sulfoxides and dialkyl sulfoxides was efficiently promoted by a mesoporous aluminosilicate Al-MCM-41 to afford the corresponding α-acetoxy sulfides in high yields. The catalyst was easily recovered by filtration and could be reused three times without a significant loss of catalytic activity.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Ito, Suguru
Kubota, Yoshihiro
Asami, Masatoshi
format Article
author Ito, Suguru
Kubota, Yoshihiro
Asami, Masatoshi
author_sort Ito, Suguru
title Pummerer Reaction of Sulfoxides in Acetic Anhydride Catalyzed by Al-MCM-41
title_short Pummerer Reaction of Sulfoxides in Acetic Anhydride Catalyzed by Al-MCM-41
title_full Pummerer Reaction of Sulfoxides in Acetic Anhydride Catalyzed by Al-MCM-41
title_fullStr Pummerer Reaction of Sulfoxides in Acetic Anhydride Catalyzed by Al-MCM-41
title_full_unstemmed Pummerer Reaction of Sulfoxides in Acetic Anhydride Catalyzed by Al-MCM-41
title_sort pummerer reaction of sulfoxides in acetic anhydride catalyzed by al-mcm-41
publishDate 2016
url https://hdl.handle.net/10356/82874
http://hdl.handle.net/10220/40364
_version_ 1681047439436414976

Similar Items