Alkyl ethers as traceless hydride donors in brønsted acid catalyzed intramolecular hydrogen atom transfer
A new protocol for the deoxygenation of alcohols and the hydrogenation of alkenes under Brønsted acid catalysis has been developed. The method is based on the use of either a benzyl or isopropyl ether as a traceless hydrogen‐atom donor, and involves an intramolecular hydride transfer as a key step,...
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sg-ntu-dr.10356-857302023-02-28T19:33:32Z Alkyl ethers as traceless hydride donors in brønsted acid catalyzed intramolecular hydrogen atom transfer Gandamana, Dhika Aditya Wang, Bin Tejo, Ciputra Bolte, Benoit Gagosz, Fabien Chiba, Shunsuke School of Physical and Mathematical Sciences DRNTU::Science::Chemistry Hydrogen Atom Transfer Brønsted Acid A new protocol for the deoxygenation of alcohols and the hydrogenation of alkenes under Brønsted acid catalysis has been developed. The method is based on the use of either a benzyl or isopropyl ether as a traceless hydrogen‐atom donor, and involves an intramolecular hydride transfer as a key step, which is achieved in a regio‐ and stereoselective manner. MOE (Min. of Education, S’pore) Accepted version 2019-05-16T07:55:04Z 2019-12-06T16:09:12Z 2019-05-16T07:55:04Z 2019-12-06T16:09:12Z 2018 Journal Article Gandamana, D. A., Wang, B., Tejo, C., Bolte, B., Gagosz, F., & Chiba, S. (2018). Alkyl Ethers as Traceless Hydride Donors in Brønsted Acid Catalyzed Intramolecular Hydrogen Atom Transfer. Angewandte Chemie International Edition, 57(21), 6181-6185. doi:10.1002/anie.201801953 1433-7851 https://hdl.handle.net/10356/85730 http://hdl.handle.net/10220/48237 10.1002/anie.201801953 en Angewandte Chemie International Edition © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the peer reviewed version of the following article: Gandamana, D. A., Wang, B., Tejo, C., Bolte, B., Gagosz, F., & Chiba, S. (2018). Alkyl Ethers as Traceless Hydride Donors in Brønsted Acid Catalyzed Intramolecular Hydrogen Atom Transfer. Angewandte Chemie International Edition, 57(21), 6181-6185., which has been published in final form at http://dx.doi.org/10.1002/anie.201801953. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. 6 p. application/pdf |
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DRNTU::Science::Chemistry Hydrogen Atom Transfer Brønsted Acid Gandamana, Dhika Aditya Wang, Bin Tejo, Ciputra Bolte, Benoit Gagosz, Fabien Chiba, Shunsuke Alkyl ethers as traceless hydride donors in brønsted acid catalyzed intramolecular hydrogen atom transfer |
| description |
A new protocol for the deoxygenation of alcohols and the hydrogenation of alkenes under Brønsted acid catalysis has been developed. The method is based on the use of either a benzyl or isopropyl ether as a traceless hydrogen‐atom donor, and involves an intramolecular hydride transfer as a key step, which is achieved in a regio‐ and stereoselective manner. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Gandamana, Dhika Aditya Wang, Bin Tejo, Ciputra Bolte, Benoit Gagosz, Fabien Chiba, Shunsuke |
| format |
Article |
| author |
Gandamana, Dhika Aditya Wang, Bin Tejo, Ciputra Bolte, Benoit Gagosz, Fabien Chiba, Shunsuke |
| author_sort |
Gandamana, Dhika Aditya |
| title |
Alkyl ethers as traceless hydride donors in brønsted acid catalyzed intramolecular hydrogen atom transfer |
| title_short |
Alkyl ethers as traceless hydride donors in brønsted acid catalyzed intramolecular hydrogen atom transfer |
| title_full |
Alkyl ethers as traceless hydride donors in brønsted acid catalyzed intramolecular hydrogen atom transfer |
| title_fullStr |
Alkyl ethers as traceless hydride donors in brønsted acid catalyzed intramolecular hydrogen atom transfer |
| title_full_unstemmed |
Alkyl ethers as traceless hydride donors in brønsted acid catalyzed intramolecular hydrogen atom transfer |
| title_sort |
alkyl ethers as traceless hydride donors in brønsted acid catalyzed intramolecular hydrogen atom transfer |
| publishDate |
2019 |
| url |
https://hdl.handle.net/10356/85730 http://hdl.handle.net/10220/48237 |
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1759854826755194880 |