Guanidine-catalyzed asymmetric Strecker reaction: modes of activation and origin of stereoselectivity
Density functional theory calculations were employed to study the catalytic mechanism, modes of activation, and origin of enantioselectivity of guanidine-catalyzed asymmetric Strecker reaction of N-benzhydryl imine with hydrogen cyanide. Two types of bifunctional activation mode were identified, nam...
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| Main Authors: | , , |
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| 格式: | Article |
| 語言: | English |
| 出版: |
2017
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| 主題: | |
| 在線閱讀: | https://hdl.handle.net/10356/86553 http://hdl.handle.net/10220/44066 |
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| 機構: | Nanyang Technological University |
| 語言: | English |