Guanidine-catalyzed asymmetric Strecker reaction: modes of activation and origin of stereoselectivity
Density functional theory calculations were employed to study the catalytic mechanism, modes of activation, and origin of enantioselectivity of guanidine-catalyzed asymmetric Strecker reaction of N-benzhydryl imine with hydrogen cyanide. Two types of bifunctional activation mode were identified, nam...
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Main Authors: | Xue, Hansong, Tan, Choon-Hong, Wong, Ming Wah |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2017
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/86553 http://hdl.handle.net/10220/44066 |
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Institution: | Nanyang Technological University |
Language: | English |
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