Combining the catalytic enantioselective reaction of visible-light-generated radicals with a by-product utilization system

Combining the catalytic enantioselective reaction of visible-light-generated radicals with a by-product utilization system

We report an unusual reaction design in which a chiral bis-cyclometalated rhodium(III) complex enables the stereocontrolled chemistry of photo-generated carbon-centered radicals and at the same time catalyzes an enantioselective sulfonyl radical addition to an alkene. Specifically, employing inexpen...

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Bibliographic Details
Main Authors: Huang, Xiaoqiang, Luo, Shipeng, Burghaus, Olaf, Webster, Richard David, Harms, Klaus, Meggers, Eric
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2017
Subjects:
By-product Utilization
Enantioselective Radicals
Online Access:https://hdl.handle.net/10356/86888
http://hdl.handle.net/10220/44207
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/86888
http://hdl.handle.net/10220/44207

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