Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress

• Main Authors: Zhang, Xi, Zhou, Yong, Gong, Yinyan, Huang, Yongli, Sun, Changqing
• Other Authors: School of Electrical and Electronic Engineering
• Format: Article
• Language: English
• Published: 2018
• Subjects: Acid Solution; Surface Stress
• Online Access: https://hdl.handle.net/10356/87399; http://hdl.handle.net/10220/44437
• Institution: Nanyang Technological University

A combination of differential phonon spectrometrics (DPS) and DFT calculations verified the essentiality of H+ ↔ H+ point fragilization and X− polarization dictating the surface stress of HX (X = Cl, Br, I) solutions. H+ ↔ H+ repulsion breaks the network regularly; X− polarization shortens and stiff...