Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress
A combination of differential phonon spectrometrics (DPS) and DFT calculations verified the essentiality of H+ ↔ H+ point fragilization and X− polarization dictating the surface stress of HX (X = Cl, Br, I) solutions. H+ ↔ H+ repulsion breaks the network regularly; X− polarization shortens and stiff...
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sg-ntu-dr.10356-873992020-03-07T13:57:29Z Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress Zhang, Xi Zhou, Yong Gong, Yinyan Huang, Yongli Sun, Changqing School of Electrical and Electronic Engineering Centre for Micro-/Nano-electronics (NOVITAS) Acid Solution Surface Stress A combination of differential phonon spectrometrics (DPS) and DFT calculations verified the essentiality of H+ ↔ H+ point fragilization and X− polarization dictating the surface stress of HX (X = Cl, Br, I) solutions. H+ ↔ H+ repulsion breaks the network regularly; X− polarization shortens and stiffens the HO bonds but lengthens and softens the O:H nonbonds in its hydration shell. The X− capability of hydrogen bond and surface stress transformation follows the order of I > Br > Cl. Observations provide fresh insight into the acid solvation network dynamics. DPS resolves solute capabilities of transforming the bonds and surface stress. Accepted version 2018-02-12T08:06:12Z 2019-12-06T16:41:01Z 2018-02-12T08:06:12Z 2019-12-06T16:41:01Z 2017 Journal Article Zhang, X., Zhou, Y., Gong, Y., Huang, Y., & Sun, C. (2017). Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress. Chemical Physics Letters, 678, 233-240. 0009-2614 https://hdl.handle.net/10356/87399 http://hdl.handle.net/10220/44437 10.1016/j.cplett.2017.04.060 en Chemical Physics Letters © 2017 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Chemical Physics Letters, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1016/j.cplett.2017.04.060]. 19 p. application/pdf |
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Nanyang Technological University |
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Singapore |
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English |
| topic |
Acid Solution Surface Stress |
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Acid Solution Surface Stress Zhang, Xi Zhou, Yong Gong, Yinyan Huang, Yongli Sun, Changqing Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress |
| description |
A combination of differential phonon spectrometrics (DPS) and DFT calculations verified the essentiality of H+ ↔ H+ point fragilization and X− polarization dictating the surface stress of HX (X = Cl, Br, I) solutions. H+ ↔ H+ repulsion breaks the network regularly; X− polarization shortens and stiffens the HO bonds but lengthens and softens the O:H nonbonds in its hydration shell. The X− capability of hydrogen bond and surface stress transformation follows the order of I > Br > Cl. Observations provide fresh insight into the acid solvation network dynamics. DPS resolves solute capabilities of transforming the bonds and surface stress. |
| author2 |
School of Electrical and Electronic Engineering |
| author_facet |
School of Electrical and Electronic Engineering Zhang, Xi Zhou, Yong Gong, Yinyan Huang, Yongli Sun, Changqing |
| format |
Article |
| author |
Zhang, Xi Zhou, Yong Gong, Yinyan Huang, Yongli Sun, Changqing |
| author_sort |
Zhang, Xi |
| title |
Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress |
| title_short |
Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress |
| title_full |
Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress |
| title_fullStr |
Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress |
| title_full_unstemmed |
Resolving H(Cl, Br, I) capabilities of transforming solution hydrogen-bond and surface-stress |
| title_sort |
resolving h(cl, br, i) capabilities of transforming solution hydrogen-bond and surface-stress |
| publishDate |
2018 |
| url |
https://hdl.handle.net/10356/87399 http://hdl.handle.net/10220/44437 |
| _version_ |
1681041481823944704 |