Mechanistic insights for the photoredox organocatalytic fluorination of aliphatic carbons by anthraquinone using time-resolved and DFT studies

• Main Authors: Kee, J. W., Shao, H., Kee, C. W., Lu, Yunpeng, Soo, Han Sen, Tan, Choon Hong
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2018
• 主題: Photoredox Catalysis; C-H Fluorination; DRNTU::Science::Chemistry
• 在線閱讀: https://hdl.handle.net/10356/87664; http://hdl.handle.net/10220/47035

Chemoselective photoredox fluorination is an appealing approach to access fluorinated fine chemicals such as active pharmaceutical ingredients, but most of the known procedures currently lack time-resolved mechanistic insights. We use nanosecond transient absorption spectroscopy and density function...